Search results for "D dimer"

showing 5 items of 5 documents

Inhibitor-Induced Dimerization of an Essential Oxidoreductase from African Trypanosomes

2018

Trypanosomal and leishmanial infections claim tens of thousands of lives each year. The metabolism of these unicellular eukaryotic parasites differs from the human host and their enzymes thus constitute promising drug targets. Tryparedoxin (Tpx) from Trypanosoma brucei is the essential oxidoreductase in the parasite's hydroperoxide-clearance cascade. In vitro and in vivo functional assays show that a small, selective inhibitor efficiently inhibits Tpx. With X-ray crystallography, SAXS, analytical SEC, SEC-MALS, MD simulations, ITC, and NMR spectroscopy, we show how covalent binding of this monofunctional inhibitor leads to Tpx dimerization. Intra- and intermolecular inhibitor-inhibitor, pro…

TrypanosomaProtein ConformationSpermidineDimerTrypanosoma brucei bruceiAntiprotozoal AgentsMolecular Dynamics SimulationTrypanosoma brucei010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundThioredoxinsBacterial ProteinsIn vivoOxidoreductaseAnimalsHumansEnzyme Inhibitorschemistry.chemical_classificationbiology010405 organic chemistryHydrogen PeroxideGeneral ChemistryNuclear magnetic resonance spectroscopyLigand (biochemistry)biology.organism_classificationGlutathione0104 chemical sciencesEnzymechemistryBiochemistryDrug DesignChemically induced dimerizationProtein MultimerizationOxidoreductasesOxidation-ReductionProtein BindingAngewandte Chemie International Edition
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Crystal structure of diethyl 2-amino-5-{4-[bis-(4-methyl-phen-yl)amino]-benzamido}-thio-phene-3,4-di-carboxyl-ate.

2019

The title compound forms a head-to-head centrosymmetric dimer, involving a pair of inter­molecular N—H⋯O hydrogen bonds. It also forms two intra­molecular bonds between its amine and amide and the ester carbonyl groups.

inorganic chemicalscrystal structureintra- and intermolecular bondingThio-hydrogen-bonded dimerCrystal structure010402 general chemistryRing (chemistry)01 natural sciencesMedicinal chemistryResearch Communicationslcsh:Chemistrychemistry.chemical_compoundAmideGeneral Materials SciencePhene010405 organic chemistryHydrogen bondRegioselectivityGeneral ChemistryCondensed Matter Physics3. Good health0104 chemical scienceslcsh:QD1-999chemistryintra- and inter­molecular bondingAmine gas treatingActa crystallographica. Section E, Crystallographic communications
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Guest-Induced Folding of the N-Benzyl Substituents in an Ammonium Resorcinarene Chloride and the Formation of a Halogen-Bonded Dimer of Capsules

2016

In methanol, N-benzyl ammonium resorcinarene chloride (Bn-NARCl) crystallizes as a solvate with the benzyl groups oriented in an open flower-like manner parallel to the cation–anion seam. 1,4-Dioxane as guest triggers a “semi-closed” single-molecule capsule with two benzyl “arms” enclosing the guest. The introduction of halogen bond (XB) donor 1,4-diiodoperfluorobutane (1,4-DIOFB) additionally folds the remaining two benzyl arms thus resulting in a fully closed capsule. Two 1,4-DIOFB molecules bridge two such Bn-NARCl capsules, forming a 2:2:2 XB held dimeric assembly of single-molecule capsules. The peculiar behavior was not observed in the bromide analog under similar experimental conditi…

capsulessupramolecular self-assembly processesStereochemistryDimer010402 general chemistry01 natural sciencesChloridechemistry.chemical_compoundBromidemedicineMoleculeGeneral Materials Scienceta116halogen-bonded dimersHalogen bondta114thermodynamically disfavored conformations010405 organic chemistryGeneral ChemistryResorcinareneCondensed Matter Physics0104 chemical sciencesCrystallographychemistryHalogenSingle crystalmedicine.drugCrystal Growth & Design
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Deferment of Objective Assessment of Deep Vein Thrombosis and Pulmonary Embolism Without Increased Risk of Thrombosis

2004

Background: Treatment of patients with suspected deep vein thrombosis (DVT) or pulmonary embolism (PE) is problematic if diagnostic imaging is not immediately available. Pretest clinical probability (PCP) and D-dimer assessment can be used to identify patients for whom empirical protective anticoagulation is indicated. To evaluate whether PCP and D-dimer assessment, together with the use of low-molecular-weight heparins (LMWHs), allow objective appraisal of DVT and PE to be deferred for up to 72 hours, patients with suspected DVT and PE were prospectively examined. Methods: Patients identified with a high PCP or a moderate PCP with positive D-dimer test results received a protective full-do…

AdultMalemedicine.medical_specialtyAdolescentmedicine.drug_classDeep veinLow molecular weight heparinFibrin Fibrinogen Degradation ProductsD-dimerInternal MedicinemedicineHumansRisk factoranticoagulationAgedAged 80 and overVenous ThrombosisPatientVascular diseasebusiness.industrylow molecular weight heparinAnticoagulantdeep vein thrombosisuspected PEHeparin Low-Molecular-WeightMiddle Agedmedicine.diseaseThrombosisSurgeryPulmonary embolismmedicine.anatomical_structureD dimerFemalePulmonary EmbolismbusinessAlgorithmsFollow-Up StudiesArchives of Internal Medicine
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Correlation Analysis of Anti-Cardiolipin Antibody/D Dimer/C-Reactive Protein and Coronary Artery Lesions/Multiple-Organ Damage in Children With Kawas…

2021

Aim: Kawasaki disease (KD) is a systemic vasculitis with unknown etiology. In addition to cardiovascular system involvement, it can also have other multiple organs involved. This study is aimed at investigating the correlation between anti-cardiolipin antibody (ACA)/D dimer/C reactive protein (CRP) and coronary artery lesions (CAL)/multiple-organ lesions in children with KD.Methods: Retrospective analysis was performed in 284 KD/IKD patients from May 2015 to April 2016. Among them, 175 were males (61.6%), with average age of 2 years and 5 months old. Patients were divided into ACA+ group and ACA- group, elevated D dimer group (DDE) and normal D dimer group (DDN), and coronary artery injury …

coronary artery lesions (CALs)medicine.medical_specialtyPediatricsGastroenterologyRJ1-570HypoproteinemiachildrenCholestasisInternal medicineD-dimermedicineOriginal ResearchThrombocytosisbiologybusiness.industryC-reactive proteinanticardiolipin antibody (ACA)medicine.diseaseC reactive protein (CRP)stomatognathic diseasesmedicine.anatomical_structureKawasaki disease (KD)Pediatrics Perinatology and Child HealthD dimerbiology.proteinKawasaki diseasebusinessmultiple organ damageSystemic vasculitisArteryFrontiers in Pediatrics
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